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Question

Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed by 2K. (Kf of water =1.86 K kg mol1)

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Solution

i=2
WA=1 kg=1000 g
ΔTf=2k
Kf=1.86 k kg mol1
HB=74.5 g/mol1
substituting those values in expansion
WB=(ΔTf)(HB)(WA)iKf(1000)
=(2)(745)(1000)(2)(186)(1000)
amount of Kd to added =40.05 moles

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