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Question

Calculate, the ΔH at 85oC for the reaction:
Fe2O3(s)+3H22Fe(s)+3H2O(l)
The data are: ΔHo298 =33.29 kJ/mol and
SubstanceFe2O3(s)Fe(s)H2O(l)H2(g)
CoP(J/Kmol)103.825.175.328.8

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Solution

Fe2O3(s)+3H22Fe(s)+3H2O(l)
ΔCP=(CP)P(CP)R=(2×25.1+3±75.3)(103.8+3×28.8)=85.9J
ΔHT2ΔHT1T2T1=ΔCP
ΔH358(33.29)358298=85.9×103
ΔH358=28.14kJ/mol

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