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Question

Calculate the entropy change at 373 K for the following transformation.
H2O(I,1.01325bar)H2O(g,0.101325bar). Given ΔvapH(H2O)=37.3kJmol1

A
19.14JK1mol1
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B
119.14JK1mol1
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C
80.86JK1mol1
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D
180.86JK1mol1
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Solution

The correct option is C 119.14JK1mol1
Step I : H2O(I,1.01325bar)H2O(g,0.101325bar)
Δs1=37.3×103373KJmol1=100JK1mol1
Step II : H2O(I,1.01325bar)H2O(g,0.101325bar)
Δs2=RInP1P2=8.314JK1mol1×2.303×log1.013250.101325=19.1
ΔS=ΔS1+ΔS2=100JK1mol1+19.147JK1mol1=119.14

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