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Question

Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.

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Solution

Let the total mass of the solution be 100 g and the mass of benzene be 30 g.

Mass of carbon tetrachloride = (100 − 30)g

= 70 g

Molar mass of benzene (C6H6) = (6 × 12 + 6 × 1) g mol−1

= 78 g mol−1

Number of moles of

= 0.3846 mol

Molar mass of carbon tetrachloride (CCl4) = 1 × 12 + 4 × 355

= 154 g mol−1

Number of moles of CCl4

= 0.4545 mol

Thus, the mole fraction of C6H6 is given as:

= 0.458


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