The correct option is D 5×1014Hz
Using eVs=hcλ−ϕ
where ϕ is the work function of metal, hc=1241 eV if wavelength is put in nm.
Case 1: λ=550 nm Vs=0.19 V
∴ 0.19 eV=1241550 eV−ϕ
Or 0.19 eV=2.256 eV−ϕ
⟹ ϕ=2.07 eV
Threshold frequency for the surface νth=ϕh=2.07×1.6×10−196.62×10−34=5×1014 Hz