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Question

Calculate the volume fo HCL gas formed and chlorine gas required when 40 mL of methane reacts completely with chlorine at STP.
CH4+2Cl2CH2Cl2+2HCl

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Solution

CH4+2Cl2CH2Cl2+2HCl

Here, we see that 1 mole of CH4 react with 2 mole ofC l subscript 2 to form 1 mole of CH2Cl2and 2 mole HCl.

it means 1 mole of C H subscript 4 , forms 2 mole of HCl .

so, 1 volume ofC H subscript 4 forms 2volume of HCl.

hence,
40 ml of C H subscript 4 forms 2 × 40ml HCl

hence, volume of HCl = 80 ml

1 volume of CH4 reacts with 2 volume of chlorine.

40 ml of CH4 reacts with 80 ml of chlorine.


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