The correct option is B CaCO3, CuSO4.5H2O
Carbon and hydrogen in an organic compound are detected as CaCO3 & CuSO4⋅5H2O respectively.
The organic compound is heated with dry copper oxide . C and H of the organic compound are oxidized to carbon dioxide and water.
Carbon dioxide is detected by passing it through lime to form calcium carbonate and the presence of hydrogen is detected by passing it through anhydrous copper sulfate (white) which turns blue on hydration CuSO4.5H2O (hydrated copper sulfate).