Carbon monoxide is allowed to expand isothermally and reversibly from 15m3to30m3 at 300K and work obtained is 8.595kJ. Calculate the number of moles of carbon monoxide. Take R = 8.3 JK−1mol−1 and ln2 = 0.69
A
5.00mol
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B
4.72mol
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C
3.33mol
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D
7.82mol
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Solution
The correct option is A5.00mol Work done in an isothermal reversible process is given as: w=−nRTlnV2V1
Given: V1=15m3 V2=30m3 T=300K R=8.3JK−1mol−1 W=−8.585×103J
(as work is done by the system)
So, −8.595×103=−n×8.3×300×ln2010