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Question

Catalytic hydrogenation of which of following will yields isopentane?

A
CH3CH=C(CH3)2
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B
CH3CH2C||CCH2H3
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C
CH3CH2C|=CH3CH2
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D
CH2=CHCH(CH3)2
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Solution

The correct option is A CH3CH=C(CH3)2
In a hydrogenation reaction, two hydrogen atoms are added across the double bond of an alkene, resulting in a saturated alkane. Hydrogenation of a double bond is a thermodynamically favorable reaction because it forms a more stable (lower energy) product.

Common catalysts used are insoluble metals such as platinum in the form PtO2. With the presence of a metal catalyst, the H-H bond in H2 cleaves, and each hydrogen attaches to the metal catalyst surface, forming metal-hydrogen bonds.

CH3CH=C(CH3)2+H2CH3CH2CH(CH3)2whichisisopentane

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