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Question

Catalytic union of H2 and O2to get H2O2 is:

A
auto oxidation
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B
electrolysis of 50%Na2O2
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C
hydrolysis of aqueous solution of (NH4)2SO4+H2SO4
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D
treating Na2O2 with cold dil. Na2O2
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Solution

The correct option is B auto oxidation
Auto oxidation is any oxidation that occurs in open air or in presence of oxygen and UV radiation and forms peroxides and hydroperoxides. A classic example of autoxidation is that of simple ethers like diethyl ether, whose peroxides can be dangerously explosive. It can be considered to be a slow, flameless combustion of materials by reaction with oxygen. Autoxidation is important because it is a useful reaction for converting compounds to oxygenated derivatives, and also because it occurs in situations where it is not desired (as in the destructive cracking of the rubber in automobile tires).

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