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Question
CH3−CH2−OHK2Cr2O7+H2SO4−−−−−−−−−−−→oxidationAK2Cr2O7+H2SO4−−−−−−−−−−−→oxidationBNH3→C−H2O→DBr2/KOH−−−−−−−−−−−−−→halffmanbromamideEHONO−−−−→−N2F
What is B?
What is B?
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Solution
The correct option is C CH3−COOH
The compound F is a mixture of methyl nitrite and dimethyl ether. CH3−CH2−OHK2Cr2O7+H2SO4−−−−−−−−−−−→ oxidation CH3−CHOA, acetaldehyde K2Cr2O7+H2SO4−−−−−−−−−−−→ oxidationCH3−COOHB, acetic acid NH3→CH3−COO−NH+4C, ammonium acetate −H2O→CH3−CONH2D, acetamide BR2/KOH−−−−−−−−−−−−−−−−−−−−−→ Hoffmann bromamide degradation CH3−NH2E, methylamine HONO−−−−→−N2CH3−O−N=O+CH3−O−CH3F, methyl nitrite + dimethyl ether
The compound F is a mixture of methyl nitrite and dimethyl ether.
CH3−CH2−OHK2Cr2O7+H2SO4−−−−−−−−−−−→ oxidation CH3−CHOA, acetaldehyde K2Cr2O7+H2SO4−−−−−−−−−−−→ oxidationCH3−COOHB, acetic acid NH3→CH3−COO−NH+4C, ammonium acetate −H2O→CH3−CONH2D, acetamide BR2/KOH−−−−−−−−−−−−−−−−−−−−−→ Hoffmann bromamide degradation CH3−NH2E, methylamine HONO−−−−→−N2CH3−O−N=O+CH3−O−CH3F, methyl nitrite + dimethyl ether
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