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Question

CH3−CH3Pyrolysis−−−−−−→A

A1000−2000atm,traces of O2,Δ−−−−−−−−−−−−−−−−−−→C6H5−CO−O−O−CO−C6H5B

AZiegler−Natta Catalyst−−−−−−−−−−−−−−→6−7atm,ΔC
Here, B and C are :

A
LDPE, HDPE
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B
HDPE, LDPE
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C
LDPE, LDPE
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D
HDPE, HDPE
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Solution

The correct option is A LDPE, HDPE
Product B and C are polyethene.
The low density polythene (LDP) is obtained by the polymerisation of ethene under high pressure of 1000 to 2000 atm at a temperature of 350 K to 570 K in the presence of traces of dioxygen or a peroxide initiator (catalyst).
The low density polythene (LDP) is obtained through the free radical addition and H-atom abstraction has highly branched structure.
The high density polyethene is
formed when addition polymerisation of ethene takes place in a hydrocarbon solvent in the presence of a catalyst such as triethylaluminium and titanium tetrachloride (Ziegler-Natta catalyst) at a temperature of 333 K to 343 K and under a pressure of 67 atm. High density polythene (HDP) thus, produced consists of linear molecules and has a high density due to close packing.

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