CH3-CH3-CH-CH2-CH3-Br2 P Major product on monobromination The product P is -

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Preparation of Haloalkanes from Alcohol

CH3-CH3|CH-CH...

Question

$C H_{3} - C H_{3} | C H - C H_{2} - C H_{3} + B r_{2} h v - \to$ P (Major product)
(on monobromination)
The product P is :

C H_{3} - B r | C | C H_{3} - C H_{2} - C H_{3}

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C | B r H_{2} - C | C H_{3} H - C H_{2} C H_{3}

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C H_{3} - C H_{3} | C H - C | B r H - C H_{3}

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H_{3} C - C H_{3} | C H - C H_{2} - C H_{2} B r

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S_{N} 2

K I

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H ∣ C H_{3} - C H_{2} - C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{2} - C H_{2} - B r

(I) (I I)

C H_{3} - C H ∣ C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{3} ∣ C ∣ C H_{3} - C H_{2} C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - B r ∣ C H - C H_{3} a n d C H_{3} - C H_{3} ∣ C H - C H_{2} - B r ∣ C H - C H_{3}

(I) (I I)

(A) C H_{3} - C H_{2} - C | B r H - + C H - C H_{3}

(B) C H_{3} - C H_{2} - C | I H - + C H - C H_{3}

C H_{3} - C H_{2} - \oplus C H_{2}

C H_{3} - C H | F - \oplus C H_{2}

C H_{3} - C H | B r - \oplus C H_{2}

C H_{3} - C H | C l - \oplus C H_{2}

{CH}_{3} - {CH}_{2} - Br + {CH}_{3} - {CH}_{2} - Br Na / dry ether - ------- \to The product / s formed are

A . C H_{3} - C H = C H_{2} + H C l ⟶ C H_{3} - C | C l H - C H_{3}

B . C H_{3} - C H = C H_{2} + H B r ⟶ C H_{3} - C H_{2} - C H_{2} B r

C . C H_{3} - C H = C H_{2} + H B r p e r o x i d e - ---- \to C H_{3} - C H_{2} - C H_{2} - B r

D . C H_{3} - C H = C H_{2} + H I p e r o x i d e - ---- \to C H_{3} - C | I H - C H_{3}

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