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Question

Chlorination of alkanes is a photochemical process. It is initiated by the process of:

A
heterolysis
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B
homolysis
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C
pyrolysis
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D
hydrolysis
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Solution

The correct option is A homolysis
Photochemical chlorination of alkane takes place by free radical mechanism which are possible by homolysis of ClCl bond by sunlight.
Cl2hνCl+Cl
CH3CH3+ClCH2CH3+HCl
ClCl+CH2CH3ClCH2CH3+Cl

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