The correct option is C To err
The infinitive verb is a verb with the word 'to' in front of it. This verb is always just a verb. There is no - ed, no - ing, no - s at the end of the verb. Here, the infinitive verb is used as a subject of the sentence. Thus, options A, B and C are wrong according to the rule. The correct option is D since 'to' is used as subject of the sentence. Hence, sentence would become: To err is human.