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Question

Choose the correct order of alkyl group attached to aldehyde that prefer the nucleophilic addition at carbonyl carbon?

A
primary > tertiary > secondary
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B
primary > secondary > tertiary
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C
tertiary > secondary > primary
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D
secondary > tertiary > primary
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Solution

The correct option is B primary > secondary > tertiary
As the alkyl group in aldehyde increases, carbonyl carbon becomes a weak electrophile due to alkyl +I effect and the reactivity toward nucleophilic addition becomes low.
Hence,
primary > secondary > tertiary

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