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Question

Choose the correct statements regarding PCl5

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Solution

Phosphorus contains 5 valence electrons. In PCl5 five atomic orbitals combine to form five hybrid orbitals resulting in five covalent bonds with five chlorine atoms. Out of which two are axial and three are in equatorial position.
Therefore, PCl5 molecules have sp3d hybridization and therefore a trigonal bipyramidal structure.

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