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Byju's Answer
Standard XII
Chemistry
Electrochemical Cells, Galvanic Cells
Combination o...
Question
Combination of
P
t
(
I
V
)
,
N
H
3
,
C
l
−
,
K
+
result in the formation of
x
complexes and one such complex is
[
P
t
(
N
H
3
)
6
]
C
l
4
.
x
is :
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Solution
[
P
t
(
N
H
3
)
5
C
l
]
C
l
3
[
P
t
(
N
H
3
)
4
C
l
2
]
C
l
2
[
P
t
(
N
H
3
)
3
C
l
3
]
C
l
−
[
P
t
(
N
H
3
)
2
C
l
4
]
K
+
[
P
t
(
N
H
3
)
C
l
5
]
K
2
[
P
t
C
l
6
]
One complex is given.
Hence, the value of
x
is 7.
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Similar questions
Q.
[
P
t
(
N
H
3
)
6
]
C
l
4
complex gives :
Q.
A complex containing K
+
, Pt(IV) and Cl
−
is 100% ionised giving
i
=
3. Thus, the complex is :
Q.
What is the value of
x
in
P
t
C
l
4
⋅
x
N
H
3
to form
[
P
t
(
N
H
3
)
6
]
C
l
4
?
Q.
One molecule of
[
P
t
(
N
H
3
)
6
]
C
l
4
gives five ions in solution and required (
x
mole) of
A
g
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for complete precipitation of chloride ions.
The value of x is :
Q.
The formation of molecular complex
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