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Question

Compare rate of reaction with AgNO3 or rate SN1 reaction:
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A
i > ii > iii
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B
ii > iii > i
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C
ii > i > iii
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D
i > iii > ii
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Solution

The correct option is A i > ii > iii
The Rate of reaction with AgNO3 is (i) > (ii) > (iii).

Rate is directly proportional to
  1. Weak nucleophile with low concentration is required
  2. Better leaving group is required for the reaction
  3. Formation of carbocation should be stable
  4. Alkyl halide is sterically hindered
  5. Polar protic solvent with high dielectric constant is required

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