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Question

Complete the following chemical reaction:
C2H5NH2+CS2+HgCl2heat....+HgS+HCl

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Solution

Hofmann mustard oil reaction: It is given only by primary amines. Ethyl isothiocyanate (the product) has pungent smell similar to mustard oil. Hence, this reaction is test for primary amines.
C2H5NH2+CS2+HgCl2heatC2H5N=C=S Ethyl isothiocyanate +HgS+HCl

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