Complete the following reactions -i R-CH2-OH -ii CH3-CH-CH2-H2O H- - -

1) Reaction of primary alcohol with metal gives aldehydes; R CH_2 OH R CO H 2) Reaction of alkene with water gives alcohol. CH_3 CH=CH_2+H_2O CH_3 CH( ...

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Standard XII

Chemistry

Oxidation of Alcohols

Complete the ...

Question

Complete the following reactions :
i) $R - C H_{2} - O H C u - -- \to 573 K . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .$
ii) $C H_{3} - C H = C H_{2} + H_{2} O^{+} . . . . . . . . . . . . . . . . . . . . . . . . . . .$

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Solution

1) Reaction of primary alcohol with metal gives aldehydes;
$R - C H_{2} - O H C u, 575 K - ----- \to Δ R - C O - H$

2) Reaction of alkene with water gives alcohol.
$C H_{3} - C H = C H_{2} + H_{2} O H^{+} - - \to C H_{3} - C H (O H) - C H_{3}$

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Q. Complete the following chemical reactions and write the products.
(i)

C H_{3} - C H_{2} - C l + K O H (a l c .) \to

(ii)

R - C H = C H_{2} + H B r P e r o x i d e - ---- \to

Q. State the IUPAC names of the following compounds :
(i)

C H_{3} - C H_{2} - C H_{2} - O H

(ii)

H C O O H

(iii)

C H_{3} - C H_{2} - C H = C H_{2}

Q. Identify the type of the following reaction of carbon compounds.
a. CH₃ -CH₂ -CH₂-OH → CH₃ -CH₂ -COOH
b. CH₃ -CH₂ -CH₃ → 3CO₂ + 4H₂O
c. CH₃ -CH = CH -CH₃ + Br₂ → CH₃ -CHBr - CHBr -CH₃
d. CH₃ -CH₃ + Cl₂→ CH₃ -CH₂ -Cl + HCl
e. CH₃-CH₂ -CH₂ -CH₂ -OH → CH₃ -CH₂ -CH=CH₂ + H₂O
f. CH₃-CH₂ -COOH + NaOH → CH₃ -CH₂ -COO - Na⁺ + H₂O
g. CH₃ -COOH + CH₃ -OH → CH₃ -COO- CH₃ + H₂O

Q. Complete the following chemical reactions
(b)

C H_{3} - C H_{2} - C l + K C N Δ - \to

(c)

C H_{3} - C H = C H_{2} + H I \to

(d)

C H_{3} - C H_{2} - O H + N a B r + H_{2} S O_{4} \to

Q. Give the IUPAC name of the following compounds:

C H_{3} - C H_{2} - O H | C H - C H_{2} - C H_{2} - C H_{2} - C H_{2} - C H_{2} - C H_{2} - C H_{2} - C H_{2} - C H_{3} | C H - C H_{3}

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Complete the following reactions :i) R−CH2−OHCu−−−→573K......................................ii) CH3−CH=CH2+H2OH+⇌...........................

1) Reaction of primary alcohol with metal gives aldehydes;R−CH2−OHCu, 575 K−−−−−−→ΔR−CO−H2) Reaction of alkene with water gives alcohol.CH3−CH=CH2+H2OH+−−→CH3−CH(OH)−CH3

Complete the following reactions :
i) $R - C H_{2} - O H C u - -- \to 573 K . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .$
ii) $C H_{3} - C H = C H_{2} + H_{2} O^{+} . . . . . . . . . . . . . . . . . . . . . . . . . . .$

1) Reaction of primary alcohol with metal gives aldehydes;
$R - C H_{2} - O H C u, 575 K - ----- \to Δ R - C O - H$

2) Reaction of alkene with water gives alcohol.
$C H_{3} - C H = C H_{2} + H_{2} O H^{+} - - \to C H_{3} - C H (O H) - C H_{3}$