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Stoichiometry

Compound A A ...

Question

Compound A $A (C_{10} H_{6})$ liberates 2 mole of $C H_{4}$ when treated with MeMgBr. On heating with $K M n O_{4}$ solution, “A” produces benzene dicarboxylic acid which on mononitration produces only one product and no other isomers. The compound “A” can be:

A

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B

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C

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D

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Solution

The correct option is B
“B” Contains two acidic hydrogen and

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Compound $A (C_{10} H_{6})$ liberates 2 mole of $C H_{4}$ when treated with MeMgBr. On heating with $K M n O_{4}$ solution, “A” produces benzene dicarboxylic acid which on mononitration produces only one product and no other isomers. The compound “A” can be:

Q. An organic compound 'A' on treatment with

N H_{3}

gives 'B', which on heating gives 'C'. 'C', when treated with

B r_{2}

in the presence of KOH, produces ethylamine. Compound 'A' is:

Q. Upon heating with acidic

K M n O_{4}

, an organic compound produces

h e x a n - 1, 6 - d i o i c

acid as the major product, The starting compound is:

Compound A on sulphonation with oleum forms benzene sulphonic acid, which on heating with NaOH and acidification yields phenol. What is Compound A?

Given compound (A) upon treatment with

K M n O_{4} / H^{+}

gives (B), which on heating with ammonia produces (C). (C) on treatment with

B r_{2} / N a O H

produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of

K O H

followed by acidification gives (F).

(D) is:

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