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Question

Consider the following statements

S1 : Generally square planar complexes show geometrical isomerism but do not exhibit optical isomerism because they do not possess plane of symmetry

S2:Δt=49Δo

S3 : In octahedral complexes each electron entering the t2g orbtials stabilizes the complex ion by 0.4 Δo and each electron entering the eg orbital destabilizes the complex by an amount of 0.6 Δo


  1. S1 and S3 are correct

  2. S2 and S3 are correct

  3. S1 is incorrect.

  4. S2 and S3 are incorrect.


Solution

The correct options are
B

S2 and S3 are correct


C

S1 is incorrect.


S1 : Square planar complexes with symmetrical ligands like (en) do not show geometrical isomerism and they have plane of symmetry, so optically inactive

S2 and S3 are correct statements.

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