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Question

Correct order of freezing point of given solution
I. 0.1 M glucose II. 0.2 M urea
III. 0.1 M NaCl IV. 0.5 M CaCl2

A
I < II = III < IV
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B
I > II > III > IV
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C
III = II < IV < I
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D
IV > II > III > I
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Solution

The correct option is A I < II = III < IV
(I) 0.1M Glucose It will not be dissociated in solution, so final concentration will be 0.1M.
(II) 0.2M Urea It will also not be dissociated; final concentration= 0.2M
(III) 0.1M NaCl It will dissociate into Na+ & Cl to produce two ions. Final concentration= 0.1×2=0.2M
(IV) 0.5M CaCl2 Dissociate to produce 3 ions. Final concentration= 0.5×3=1.5M
Correct order is:- IV>III=II>I

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