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Question

Correct statement(s) is/are:

A
Diamond has more thermal conductivity than graphite
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B
1 mol of Mg2C3 reacts with water to give 3 mol of C3H4 gas
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C
The order of the lewis acidic strength is: BF3>BCl3>BBr3
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D
Aqueous solution of borax is basic in nature
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Solution

The correct option is D Aqueous solution of borax is basic in nature
a) Diamond has more thermal conductivity than graphite.
b) Mg2C3+4H2O2Mg(OH)2+C3H4
So 1 mol of Mg2C3 reacts with water to give 1 mol of C3H4.
c) The order of the Lewis acidic strength is: BF3<BCl3<BBr3. This is because of back bonding. As the side atom gets bigger, the orbital overlap with boron decreases. So, the extent of back bonding decreases and so does the electron deficit on boron.
d) Chemical formula of borax is Na2[B4O5(OH)4].8H2O. Thus, it is a salt of NaOH (strong base) and H3BO3 (weak acid). So, aqueous solution of borax is basic in nature.

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