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Colours in Coordination Compounds

Crystal field...

Question

Crystal field stabilization energy for the complex ion [FeF6]⁴- is: 1)-4Dq 2)-24Dq 3)-16Dq 4)-20Dq

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Q. Which of the following is not correctly matched?

	Complex ion	CFSE
a	$[C o (N H_{3})_{6}]^{3 +}$	$24 D q$
b	$[C r (N H_{3})_{6}]^{3 +}$	$12 D q$
c	$[F e F_{6}]^{3 -}$	$4 D q$
d	$[F e (C N)_{6}]^{3 -}$	$20 D q$

Q. Crystal field stabilization energy for high spin

d^{4}

octahedral complex is:

Q. Calculate crystal field stabilization energy for the complex

[C u (N H_{3})_{6}]^{2 +}

.

Which of the following pairs of complex ions has higher value of Crystal Field Stabilization Energy (CFSE) and why?

[C o (N H_{3})_{4}]^{2 +}

[C o (N H_{3})_{6}]^{2 +}

Q. The complex ion that will lose its crystal field stabilization energy upon oxidation of its metal to

+ 3

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