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Question

Cu2+ has a stronger polarising power than that of Ca2+ because :

A
Cu2+ ion is smaller than Ca2+ ion
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B
Ca2+ has inert gas configuration whereas Cu2+ ion does not
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C
copper shows variable valency, calcium does not
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D
Cu2+ is smaller than Ca2+ ion and the d-electrons in Cu2+ ion shield the nucleus poorly
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Solution

The correct option is D Cu2+ is smaller than Ca2+ ion and the d-electrons in Cu2+ ion shield the nucleus poorly
As we move along a raw, radius decreases so Cu have smaller radius than Ca.
Also, d-electrons in Cu2+ ion shield the nucleus poorly so nuclear charge will be high and Cu2+ have stronger polarising power than that of Ca2+.

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