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Question

CuSO4.5H2O is blue in colour while CuSO4 is colourless. Why?

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Solution

In CuSO4.5H2O, water acts as a ligand and causes crystal field splitting. Hence, d-d transition is possible thus CuSO4.5H2O is coloured. In the anhydrous CuSO4 due to the absence of water (ligand), crystal field splitting is not possible and hence, it is colourless.


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