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Question

Define the following terms.
(a) Enthalpy of fusion.
(b) Enthalpy of atomization.

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Solution

(a) Enthaply of fusion: The enthalpy change or amount of heat absorbed that accompanies the fusion of one mole of a solid at constant temperature and pressure is called enthalpy of fusion. It is denoted by (ΔsusH).
(b) Enthalpy of atomization: The enthalpy change or amount of heat absorbed accompanying the dissociation of the molecules in one mole of a gaseous substance into free gaseous atoms at constant temperature and pressure is called enthalpy of atomization. It is also called heat of dissociation and it is represented by ΔdissH and in general as, ΔautoH.

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