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Electrolysis and Electrolytes

Derive the ex...

Question

Derive the expression for pH of hydrolysis of Ammonium carbonate (Nh4)2CO3.

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(N H_{4})_{2} C O_{3}

The degree of hydrolysis of ammonium acetate is related to its hydrolysis constant by the expression

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(C N)_{2} + 4 H_{2} O \to (N H_{4})_{2} C_{2} O_{4}

(C N)_{2} + 2 H_{2} O \to N H_{2} C O N H_{2}

11.52

[(N H_{4})_{2} C O_{3}]

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1.6 M

K M n O_{4}

p H

0.02 M

(N H_{4} C N)

[K_{1}

H C N = 4.99 \times 10^{- 9}, K_{b}

N H_{4} O H = 1.77 \times 10^{- 5}]

(i)

{N H}_{4} O H i s 4 \times 10^{- 5}

C H_{3} C O O H i s 1.8 \times 10^{- 5}

p H

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