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Question

Derive the expressions for Kp and Kc for decomposition of PCl5?

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Solution

PCl5PCl3+Cl2
Kc=[PCl3][Cl2][PCl5]
KP=PPCl3PCl2PPCl5
KP=KC(RT)Δn
KP=KC(RT)1+11
KP=KC(RT)1
KP=KC(RT)

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