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Question

Determine the osmotic pressure of a solution a solution prepared by dissolving 2.5×102g of K2SO4 in 2L of water at 250C, assuming that it is completely dissociated.
(R=0.0821 L atm K1mol1, Molar mass of K2SO4=174gmol1)

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Solution

Given, mass of K2SO4=25 mg
Volume=2 liter
Temperature=T=298 K
No. of ions produced on dissociation=3
Vant hoff factor=3
Osmotic pressure of the solution=Π=inRTV=(3)×12×0.0821×298=5.27×103 atm

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