The correct option is B 1, 3
Diborane is a colourless gas and highly toxic gas with boiling point 180 K.
Hence correct option is b.
Theory
Properties:
1. B2H6 is a colourless gas and highly toxic gas with a boiling point of 180 K.
2. Diborane catches fire spontaneously upon exposure to air.
B2H6+3O2→B2O3+3H2O
ΔCH∘=–1976 kJmol–1
It burns in oxygen releasing an enormous amount of energy. Most of the higher boranes are also spontaneously flammable in the air.