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Question

CaSO4 is insoluble but is not precipitated when excess of (NH4)2SO4 is added to CaCl2.
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Solution

Though CaSO4 is insoluble but it is not precipitated when excess of (NH4)2SO4 is added to CaCl2. This is because calcium sulphate reacts with ammonium sulphate to give a soluble ammonium complex.
The reaction is as follows:
CaSO4+(NH4)2SO4(NH4)2[Ca(SO4)2]
soluble

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