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Question

Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

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Solution

Hex-2-ene is represented as:

Geometrical isomers of hex-2-ene are:

The dipole moment of cis-compound is a sum of the dipole moments of C–CH3 and C–CH2CH3 bonds acting in the same direction.

The dipole moment of trans-compound is the resultant of the dipole moments of C–CH3 and C–CH2CH3 bonds acting in opposite directions.

Hence, cis-isomer is more polar than trans-isomer. The higher the polarity, the greater is the intermolecular dipole-dipole interaction and the higher will be the boiling point. Hence, cis-isomer will have a higher boiling point than trans-isomer.


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