Draw the structure and name the product formed if the following alcohols are oxidized. Assume that an excess of oxidizing agent is used: (i) CH3CH2CH2CH2OH (ii) 2-butenol (iii) 2-methyl-propanol
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Solution
The structure and name are:
(i) CH3CH2CH2COOH, butanoic acid
(ii) CH3−CH=CH−CHO, but-2-enal
(iii) CH3−CH(CH3)−COOH, 2-methyl propanoic acid
Primary alcohols on oxidation gives carboxylic acids in presence of excess oxidizing agent. Secondary alcohols on oxidation gives carboxylic acids in presence of excess oxidizing agent.