Draw the structures of optical isomers of- Cr C 2 O 43-03- PtCl 2 en 2-2- Cr NH 32 Cl 2 en -

[Cr(C_2O_4 )_3 ]^3 Note Trans [PtCl_2(en_2 ) ]^2+ is optically inactive. Cis [PtCl_2(en_2 ) ]^2+ Note Trans [PtCl_2(en_2 ) ]^2+ is optically inactive ...

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Byju's Answer

Standard XII

Chemistry

Optical Isomerism in Octahedral Coordination of Bidentate Ligands

Draw the stru...

Question

Draw the structures of optical isomers of:
${[C r {(C_{2} O_{4})}_{3}]}_{3}^{3 -}$

${[P t C l_{2} (e n_{2})]}_{2}^{2 +}$

$[C r {(N H_{3})}_{2} C l_{2} (e n)]^{+}$

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Solution

${[C r {(C_{2} O_{4})}_{3}]}_{3}^{3 -}$

Note Trans- ${[P t C l_{2} (e n_{2})]}_{2}^{2 +}$ is optically inactive.

$C i s - {[P t C l_{2} (e n_{2})]}_{2}^{2 +}$

Note Trans- ${[P t C l_{2} (e n_{2})]}_{2}^{2 +}$ is optically inactive.

$C i s - [C r {(N H_{3})}_{2} C l_{2} (e n)]^{+}$

Note Trans- ${[P t C l_{2} (e n_{2})]}_{2}^{2 +}$ is optically inactive.

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Similar questions

Draw the structures of optical isomers of:

(i) [Cr(C₂O₄)₃]³⁻

(ii) [PtCl₂(en)₂]²⁺

(iii) [Cr(NH₃)₂Cl₂(en)]⁺

Q. Draw the structure of optically active isomers of

[C r (C_{2} O_{4})_{3}]^{3 -}

Q. Assertion :In a coordination entity

[P t C l_{2} (e n)_{2}]^{2 +}

only the cis-isomer shows optical activity. Reason: Optical isomerism is common in octahedral complexes involving didentate ligands.

Draw all the isomers (geometrical and optical) of:
${[C o C l_{2} {(e n)}_{2}]}_{2}^{+}$

${[C o (N H_{3}) C l {(e n)}_{2}]}_{2}^{2 +}$

${[C o {(N H_{3})}_{2} C l_{2} (e n)]}_{2}^{+}$

Q. (i) What type of isomers are

[C o {({N H}_{3})}_{5} B r] {S O}_{4}

and

[C o {({N H}_{3})}_{5} {S O}_{4}] B r

? Give a chemical test to distinguish between them.
(ii) Write the structures of optical isomers of the complex ion

{[C o {(e n)}_{2} {C l}_{2}]}^{+}

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Draw the structures of optical isomers of: [Cr(C2O4)3]3− [PtCl2(en2)]2+ [Cr(NH3)2Cl2(en)]+

[Cr(C2O4)3]3− Note Trans-[PtCl2(en2)]2+ is optically inactive. Cis−[PtCl2(en2)]2+ Note Trans-[PtCl2(en2)]2+ is optically inactive. Cis−[Cr(NH3)2Cl2(en)]+ Note Trans-[PtCl2(en2)]2+ is optically inactive.

Draw the structures of optical isomers of:
${[C r {(C_{2} O_{4})}_{3}]}_{3}^{3 -}$

${[P t C l_{2} (e n_{2})]}_{2}^{2 +}$

$[C r {(N H_{3})}_{2} C l_{2} (e n)]^{+}$