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Question

E1,E2,E3 are the emf values of the three galvanic cells respectively.
(i) Zn|Zn2+1M||Cu2+0.1M|Cu
(ii) Zn|Zn2+1M||Cu2+1M|Cu
(iii) Zn|Zn2+0.1M||Cu2+1M|Cu
Which one of the following is true?

A
E2>E3>E1
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B
E3>E2>E1
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C
E1>E2>E3
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D
E1>E3>E2
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Solution

The correct option is B E3>E2>E1
For the given cell,
Ecell=Eocell0.05912log[Zn2+][Cu2+]
(i) E1=Eocell0.05912log10.1=Eocell0.05912
(ii) E2=Eocell0.05912log11=Eocell0.05912×0=Eocell
(iii) E3=Eocell0.05912log0.11=Eocell+0.05912
E3>E2>E1

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