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Question

'EA of Cl is the highest among the halogens, yet F is the strongest Oxidising agent'. Why?

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Solution

F2 is strong oxidizing agent than Cl, because-
(i) Low enthalpy of dissociation of F2, due to its small size, hydration energy is very high hence better oxidizing power.
(ii) Flourine molecules have high repulsions between lone pairs on fatons. So, they have low dissociation enthalpy i.e., strong oxidizing power.

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