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Question

EAN of Mn in Mn2(CO)10 is:

A
33
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B
34
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C
35
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D
36
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Solution

The correct option is D 36
In the given compound Atomic number of Manganese is 25 and as COCO Carbon monoxide is a neutral ligand so oxidation state of Manganese is zero.Also, the no. of electrons donated by each CO ligand is 2. Hence the,EAN = electrons of metal + electrons donated by ligands + 1 M-M delta bond.
EAN = 25+1+10=36 of each Mn atom.
Therefore option D is correct

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