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Question

The effective atomic number of Mn,in Mn2(CO)10is _____.

A
36
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B
38
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C
32
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D
34
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Solution

The correct option is C 36

The formula for effective atomic number(EAN) is => Z - O.S + 2CN

here,

Z=atomic number

O.S=oxidation state

CN=coordination number

So, FOR 2 Mn

Z=2×25

O.S=0

CN=10 (for 10 CO ) + 1 (for 1 Mn-Mn sigma bond)

Thus CN = 11

EAN = 2×25 - 0 + 11×2

50+ 22

72

Thus 72 for 2 Mn

or 72/2 for 1Mn

= 36


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