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Question

Effective atomic number of Fe in Fe2(CO)9 is:

A
35
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B
36
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C
37
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D
Cannot be calculated
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Solution

The correct option is B 36
EAN = Atomic number of the central metal+3×2 (3 terminal ligands attached to each
central atom which donate 2 electrons)+3×1(3 bridging ligands which donate 1
electron each)+1(1 Fe-Fe bond)

=26+6+3+1

=36

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