Electrochemical series is a series of elements arranged in increasing order of their reduction potential and E0H+/H2=0. The metals above H2 have – ve reduction potential, they are more reactive than hydrogen whereas metals below hydrogen are less reactive than H2. Reduction potential of metal depends upon
(i) sublimation energy (ii) ionization energy and (iii) hydration energy of ions.
Which of the following is best reducing agent?
Li
Li is best reducing agent because it has lowest standard potential and secondly Li+ is most stable due to greater hydration energy.