Enthalpy of neutralization of the reaction between CH3COOH(aq) and NaOH(aq) is -13.2 kcaleq−1 and that of the reaction between H2SO4(aq) and KOH(aq) is -13.7 kcaleq−1. The enthalpy of dissociation of CH3COOH(aq) is:
A
-0.5 kcaleq−1
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B
+0.5 kcaleq−1
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C
-26.9 kcaleq−1
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D
+0.5 kcaleq−1
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Solution
The correct option is B +0.5 kcaleq−1 Dissociation enthalpy of CH3COOH = 13.7 - 13.2 = 0.5 kcaleq−1
Therefore, 0.5 kcaleq−1 heat will be used to dissociate CH3COOH completely