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Question

Enthalpy of sublimation of a substance is equal to
(a) enthalpy of fusion + enthalpy of vaporisation
(b) enthalpy of fusion
(c) enthalpy of vaporisation
(d) twice the enthalpy of vaporisation

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Solution

(a)

Enthalpy of sublimation of a substance is equal to enthalpy of fusion + enthalpy of vaporisation.
Sublimation is, direct conversion of solid to vapour. solid vapour
Writing in two steps, we have solid liquid vapour,
solid liquid requires enthalpy of fusion
liquid vapour requires enthalpy of vaporisation


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