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Question

Enthalpy of sublimation of a substance is equal to :

A
Enthalpy of fusion + enthalpy of vapourisation
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B
Enthalpy of fusion
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C
Enthalpy of vapourisation
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D
Twice the enthalpy of vapourisation
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Solution

The correct option is D Enthalpy of fusion + enthalpy of vapourisation
SolidSublimation−−−−−−Vapour
This process occurs in two steps,
Step 1 : SolidFusion−−−Liquid
Step 2 : LiquidVaporisation−−−−−−−Vapour
Thus, Enthalpy of sublimation = Enthalpy of fusion + Enthalpy of vaporisation.

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