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Question

Equal volumes of H2 and Cl2 are mixed. How will the volume of the mixture changes after the reaction at same T and P?
  1. Unchanged
  2. Reduced to half
  3. None of these
  4. Increases two fold


Solution

The correct option is A Unchanged
According to Avogadro's hypothesis, under the conditions of same temperature and pressure,
   Volumenumber of moles

H2(g)+Cl2(g)2HCl(g)
t=0110t=completion2
Since the number of moles of the product is equal to the number of moles of the reactant, there is no change in the number of moles and hence there is no change in the volume.

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