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Question

Equilibrium constant, Kc for the reaction.

N2(g)+3H2(g2NH3(g) at 500 K is 0.061.
At a particular time, the analysis shows that composition of the reaction mixture is 3.0 mol L1N2,2.0molL1H2 and 0.5 mol L1NH3, Is the reaction at equilibrium? If not in which direction does the reaction tend to proceed to reach equilibrium?

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Solution

The given reaction is:
N2(g)+3H2(g)2NH3(g)At a particular time:3.0mol L12.0mol L10.5mol L1
Qc=[NH3]2[N2][H2]3=(0.5)2(3.0)(2.0)3=0.0104
It is given that Kc=0.061
Since QcKc, the reaction is not at equilobrium,
Since, Qc<Kc, the reaction will proceed in the forward to reach equilibrium.


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