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Question

Equilibrium constant, KC for the reaction
N2(g)+3H2(g)2NH3(g) at 500 K is 0.061
At a particular time, the analysis shows that composition of the reaction mixure is 3.0 molL1 N2,2.0 molL1H2 and 0.5 molL1 NH3. Is the reaction at equilibrium and if not in which direction does the reaction tend to proceed to reach equilibrium?

A
at equilibrium
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B
not at equilibrium, backward shift
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C
not at equilibrium, forward shift
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D
can not be predicted
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Solution

The correct option is C not at equilibrium, forward shift
N2(g)+3H2(g)2NH3(g)t=teq 3M 2M 0.5MQ=0.5×0.53×23=13×8×4=196
Q < K, system is not at equilibrium and equilibrium will be reached by shifting in forward direction

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