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Question

Equilibrium constant, KC for the reaction
N2(g)+3H2(g)2NH3(g) at 500 K is 0.061 L2 mol2.
At a particular time, the analysis shows that composition of the reaction mixure is 3.0 mol L1 N2,2.0 mol L1H2 and 0.5 mol L1 NH3. What will be the direction of equilibrium?

A
at equilibrium
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B
not at equilibrium, backward shift
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C
not at equilibrium, forward shift
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D
can not be predicted
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Solution

The correct option is C not at equilibrium, forward shift
N2(g)+3H2(g)2NH3(g)t=teq 3M 2M 0.5MQ=0.5×0.53×23=13×8×4=196
Q < K, system is not at equilibrium and equilibrium will be reached by shifting in forward direction

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